Wax refer to a class of hydrocarbons In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons from which one hydrogen atom has been removed are functional groups, called hydrocarbyls. Aromatic hydrocarbons , alkanes, alkenes, cycloalkanes and alkyne-based compounds are different types of hydrocarbons that are plastic In physics and materials science, plasticity describes the deformation of a material undergoing non-reversible changes of shape in response to applied forces. For example, a solid piece of metal or plastic being bent or pounded into a new shape displays plasticity as permanent changes occur within the material itself. In engineering, the (malleable Ductility is a mechanical property that describes the extent in which solid materials can be plastically deformed without fracture) at normal ambient temperatures. Characteristically, they melt The melting point of a solid is the temperature at which the vapor pressure of the solid and the liquid are equal. At the melting point the solid and liquid phase exist in equilibrium. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point. Because of the ability of some substances to above 45 °C (113 °F) to give a low viscosity Viscosity is a measure of the resistance of a fluid which is being deformed by either shear stress or tensile stress. In everyday terms , viscosity is "thickness". Thus, water is "thin", having a lower viscosity, while honey is "thick", having a higher viscosity. Put simply, the less viscous the fluid is, the greater liquid. Waxes are insoluble Solubility is the property of a solid, liquid, or gaseous chemical substance called solute to dissolve in a liquid solvent to form a homogeneous solution of the solute in the solvent. The solubility of a substance fundamentally depends on the used solvent as well as on temperature and pressure. The extent of the solubility of a substance in a in water but soluble in petroleum based solvent.
Waxes are secreted by many plants or animals, such as beeswax Beeswax or "Bee Sweat" is a natural wax produced in the bee hive of honey bees of the genus Apis. Worker bees have eight wax-producing mirror glands on the inner sides of the sternites (the ventral shield or plate of each segment of the body) on abdominal segments 4 to 7. The size of these wax glands depends on the age of the worker and and carnauba Carnauba, also called Brazil wax and palm wax, is a wax of the leaves of the palm, Copernicia prunifera, a plant native to and grown only in the northeastern Brazilian states of Piauí, Ceará, and Rio Grande do Norte. It is known as "queen of waxes" and usually comes in the form of hard yellow-brown flakes. It is obtained from the (a plant epicuticular wax In botany, the plant cuticle is covered by epicuticular wax mainly consisting of straight-chain aliphatic hydrocarbons with a variety of substituted groups. Common examples are paraffins in leaves of peas and cabbages, alkyl esters in leaves of carnauba palm and banana, the asymmetrical secondary alcohol 10-nonacosanol in most conifers such as). Most industrial waxes are components of fossil fuels or are synthesized from petroleum-derived compounds, such as paraffin In chemistry, paraffin is a term that can be used synonymously with "alkane", indicating hydrocarbons with the general formula CnH2n+2. Paraffin wax refers to a mixture of alkanes that falls within the 20 ≤ n ≤ 40 range; they are found in the solid state at room temperature and begin to enter the liquid phase past approximately 37°C. Earwax Earwax, also known by the medical term cerumen, is a yellowish waxy substance secreted in the ear canal of humans and many other mammals. It protects the skin of the human ear canal, assists in cleaning and lubrication, and also provides some protection from bacteria, fungi, insects and water. Excess or impacted cerumen can press against the is an oily substance found in the human ear The ear is the organ that detects sound. The vertebrate ear shows a common biology from fish to humans, with variations in structure according to order and species. It not only acts as a receiver for sound, but also plays a major role in the sense of balance and body position. The ear is part of the auditory system. Many materials such as silicone Silicones are inert, synthetic compounds with a wide variety of forms and uses. Typically heat-resistant and rubber-like, they are commonly used in cookware, medical applications, sealants, adhesives, lubricants, insulation, and breast implants wax exhibit similar properties are also described as wax or waxy.
Commercial honeycomb A honeycomb is a mass of hexagonal wax cells built by honey bees in their nests to contain their larvae and stores of honey and pollen foundation, made by pressing beeswax between patterned metal rollers.
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Classification of waxes
A wax is a type of hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons from which one hydrogen atom has been removed are functional groups, called hydrocarbyls. Aromatic hydrocarbons , alkanes, alkenes, cycloalkanes and alkyne-based compounds are different types of hydrocarbons that typically contains long-chain alkanes Alkanes are chemical compounds that consist only of the elements carbon (C) and hydrogen (H) (i.e., hydrocarbons), wherein these atoms are linked together exclusively by single bonds (i.e., they are saturated compounds). Alkanes belong to a homologous series of organic compounds in which the members differ by a constant relative molecular mass of 1 often containing ester, carboxylic acid, or alcohol groups In organic chemistry, functional groups are specific groups of atoms within molecules that are responsible for the characteristic chemical reactions of those molecules. The same functional group will undergo the same or similar chemical reaction regardless of the size of the molecule it is a part of. However, its relative reactivity can be. The structure and molecular weight of the hydrocarbon chain and the relative concentration of the functional groups determine the hardness of the wax. Natural waxes especially are mixtures of several kinds of waxes whereas petroleum-derived waxes tend to be more homogeneous. Waxes can be classified according to their sources.
Natural waxes
Plant waxes
Especially in warm climates, plants secrete waxes as a way to control evaporation and hydration.[1] The most important is Carnauba wax Carnauba, also called Brazil wax and palm wax, is a wax of the leaves of the palm, Copernicia prunifera, a plant native to and grown only in the northeastern Brazilian states of Piauí, Ceará, and Rio Grande do Norte. It is known as "queen of waxes" and usually comes in the form of hard yellow-brown flakes. It is obtained from the, a hard wax with many applications. Other more specialized vegetable waxes include candelilla wax Candelilla wax is a wax derived from the leaves of the small Candelilla shrub native to northern Mexico and the southwestern United States, Euphorbia cerifera and Euphorbia antisyphilitica, from the family Euphorbiaceae. It is yellowish-brown, hard, brittle and opaque to translucent, ouricury wax, sugarcane wax, retamo wax, jojoba oil Jojoba oil is the liquid wax produced in the seed of the jojoba (Simmondsia chinensis) plant, a shrub native to southern Arizona, southern California and northwestern Mexico. The oil makes up approximately 50% of the jojoba seed by weight. The epicuticular waxes In botany, the plant cuticle is covered by epicuticular wax mainly consisting of straight-chain aliphatic hydrocarbons with a variety of substituted groups. Common examples are paraffins in leaves of peas and cabbages, alkyl esters in leaves of carnauba palm and banana, the asymmetrical secondary alcohol 10-nonacosanol in most conifers such as of plants are mixtures of substituted long-chain aliphatic In organic chemistry, compounds composed of carbon and hydrogen are divided into two classes: aromatic compounds, which contain benzene rings or similar rings of atoms, and aliphatic compounds , which do not contain aromatic rings hydrocarbons In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons from which one hydrogen atom has been removed are functional groups, called hydrocarbyls. Aromatic hydrocarbons , alkanes, alkenes, cycloalkanes and alkyne-based compounds are different types of hydrocarbons, containing alkanes Alkanes are chemical compounds that consist only of the elements carbon (C) and hydrogen (H) (i.e., hydrocarbons), wherein these atoms are linked together exclusively by single bonds (i.e., they are saturated compounds). Alkanes belong to a homologous series of organic compounds in which the members differ by a constant relative molecular mass of 1, fatty acids, primary and secondary alcohols In chemistry, an alcohol is any organic compound in which a hydroxyl functional group (-O , diols A geminal diol has two hydroxyl groups bonded to the same atom. Examples include methanediol H2C2 and 1,1,1,3,3,3-hexafluoropropane-2,2-diol (F3C)2C(OH)2, the hydrated form of hexafluoroacetone, ketones In organic chemistry, a ketone is a compound with the structure RC(=O)R', where R and R' can be a variety of atoms and groups of atoms. It features a carbonyl group (C=O) bonded to two other carbon atoms. Acetone is the simplest example of a ketone, and in fact the word ketone derives its name from Aketon, the German word for acetone, aldehydes An aldehyde is an organic compound containing a formyl group. This functional group, with the structure R-CHO, consists of a carbonyl centre bonded to hydrogen and an R group. The group without R is called the aldehyde group or formyl group. Aldehydes differ from ketones in that the carbonyl is placed at the end of a carbon skeleton rather than.[2]
Animal waxes
The best known animal wax is beeswax but other insects secrete waxes and wool contains much wax. Beeswax is a substance secreted by bees Bees are flying insects closely related to wasps and ants, and are known for their role in pollination and for producing honey and beeswax. Bees are a monophyletic lineage within the superfamily Apoidea, presently classified by the unranked taxon name Anthophila. There are nearly 20,000 known species of bees in seven to nine recognized families, and used in constructing their honeycombs A honeycomb is a mass of hexagonal wax cells built by honey bees in their nests to contain their larvae and stores of honey and pollen. With a melting point 62 -65 °C, beeswax is primarily composed of esters with only a few percent of paraffin waxes.
Petroleum derived waxes
Paraffin waxes are hydrocarbons In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons from which one hydrogen atom has been removed are functional groups, called hydrocarbyls. Aromatic hydrocarbons , alkanes, alkenes, cycloalkanes and alkyne-based compounds are different types of hydrocarbons, mixtures of alkanes Alkanes are chemical compounds that consist only of the elements carbon (C) and hydrogen (H) (i.e., hydrocarbons), wherein these atoms are linked together exclusively by single bonds (i.e., they are saturated compounds). Alkanes belong to a homologous series of organic compounds in which the members differ by a constant relative molecular mass of 1 usually in a homologous series In chemistry, a homologous series is a series of organic compounds with a similar general formula, possessing similar chemical properties due to the presence of the same functional group, and shows a gradation in physical properties as a result of increase in molecular size and mass . For example, ethane has a higher boiling point than methane of chain lengths. These materials represent a significant fraction of petroleum. They are refined by vacuum distillation. Paraffin waxes are mixtures of saturated of n- and isoalkanes, naphthenes, and alkyl- and naphthene-substituted aromatic compounds. The degree of branching has an important influence on the properties. Million tons of paraffin waxes are produced annually. They are used as adhesives, in foods (chewing gum cheese wrapping), cosmetic, as coatings.
Montan wax
Montan wax Montan wax, also known as lignite wax or OP wax, is a hard wax obtained by solvent extraction of certain types of lignite or brown coal. Commercially viable deposits exist in only a few locations, including Amsdorf, Germany, and in the Ione Basin near Ione, California is a fossilized wax extracted from coal and lignite Lignite, often referred to as brown coal, or Rosebud coal by Northern Pacific Railroad, is a soft brown fuel with characteristics that put it somewhere between coal and peat. It is considered the lowest rank of coal; it is mined in Germany, Russia, the United States, Australia and many European countries, and it is used almost exclusively as a. It is very hard, reflecting the high concentration of saturated fatty acids In chemistry, especially biochemistry, a fatty acid is a carboxylic acid with a long unbranched aliphatic tail , which is either saturated or unsaturated. The most occurring natural fatty acids have an even number of carbon atoms because their biosynthesis involves acetyl-CoA, a coenzyme carrying a two-carbon-atom group (see fatty acid synthesis) and alcohols, not esters that characterize softer waxes. Although dark brown and smelly, they can be purified and bleached to give commercially useful products.
Polyethylene and related derivatives
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Waxes are obtained by cracking polyethylene by heating for a few minutes at 400 °C. The products have formulas of about (CH2)nH2, where n is about 50 or 100. As of 1995, about 200 million kilograms/y were consumed.[citation needed]
Uses of wax
Waxes are mainly consumed industrially as components of complex formulations, often for coatings.[1] The main use of polyethylene and polypropylene waxes is in the formulation of colourants for plastics. Waxes confer matting effects and wear resistence to paints. Polyethyelene waxes are incorporated into inks in the form of dispersions to decrease friction. They are employed as release agents A release agent is a chemical used to get a slip effect. It can provide a solution in processes involving mold release, die-cast release, plastic release, and tire and web release. They are also used as slip agents, e.g. in furniture, and corrosion resistence.
Candles
Waxes and hard fats such as tallow Tallow is a rendered form of beef or mutton fat, processed from suet. It is solid at room temperature. Unlike suet, tallow can be stored for extended periods without the need for refrigeration to prevent decomposition, provided it is kept in an airtight container to prevent oxidation have long been use to make candles A candle is a solid block of fuel and an embedded wick, which is lit to provide light, and sometimes heat.[citation needed], used for lighting and decoration in a number of religious traditions, including Christianity and Hinduism, as well as various neo-pagan religions such as Wicca. The Emperor Constantine is reported to have called for the use of candles during an Easter service in the 4th century AD. Candles continue to be used today by Christians[3] in worship as symbols of the light of Christ. In the Roman Catholic Church, beeswax candles are used, since a colony of bees is a celibate sisterhood with a single mother.[4] Candles of wax or tallow took the place of lamps used in various Jewish rituals such as the Sabbath lights; in the Havdalah ceremony; and the Hanukkah lights. A synagogue had to be well lit, and pious folk used to donate candles for the purpose. On the basis of the verse: 'The soul of man is a candle of the Lord' a special candle which burns twenty-four hours is kindled on the anniversary of the death of a near relative (Yahrzeit) and often two lighted candles are placed at the head of the corpse awaiting burial.[5]. Candles have also played a role in pagan Paganism is a blanket term, typically used to refer to polytheistic religious traditions, although from a Christian perspective, the term can encompass all non–Abrahamic religions religions and in modern humanist festivals. Virtually all rituals in Wicca Wicca is a Neopagan religion and a form of modern witchcraft. It is often referred to as Witchcraft or the Craft by its adherents, who are known as Wiccans or Witches. Its disputed origins lie in England in the early 20th century, though it was first popularised during the 1950s by Gerald Gardner, a retired British civil servant, who at the time include the lighting of altar candles, where two main candles are often used to represent the God and the Goddess; and the lighting of candles is a central theme at the Wiccan holiday of Brigid or Imbolc, which is also known as Candlemas or the Feast of the Waxing Light. Wax candles were also used in secular For instance, eating and bathing may be regarded as examples of secular activities, because there may not be anything inherently religious about them. Nevertheless, both eating and bathing are regarded as sacraments in some religious traditions, and therefore would be religious activities in those world views. Saying a prayer derived from life for lighting, signals in warfare, safety in travel and for time keeping, and are still in popular use today to provide soft lighting for meals and other social activities.
Other uses
A typical modern wax sculpture of Cecilia Cheung Cecilia Cheung Pak-Chi is a Hong Kong actress and cantopop singer based in Hong Kong. She is the wife of Nicholas Tse, thus being the daughter-in-law of Patrick Tse and Deborah Lee (狄波拉). She and Nicholas have a son, Lucas. She is considered a "Sing girl"—an actress who first received media attention through starring alongside at Madame Tussauds Hong Kong. Wax-decorated Easter eggs Easter eggs or spring eggs are special eggs that are often given to celebrate Easter or springtime as made in Ukraine Ukraine (pronounced /juːˈkreɪn/ ew-KRAYN; Ukrainian: Україна, transliterated: Ukrayina, [ukrɑˈjinɑ]), with its area of 600,000 sq km, is the second largest country in Eastern Europe. It is bordered by the Russian Federation to the east and northeast, Belarus to the northwest, Poland, Slovakia and Hungary to the west, Romania and and the Czech Republic The Czech Republic (pronounced /ˈtʃɛk/ chek; Czech: Česká republika, pronounced [ˈtʃɛskaː ˈrɛpuˌblɪka] ( listen), short form Česko [ˈtʃɛskɔ]) is a landlocked country in Central Europe. The country borders Poland to the northeast, Germany to the west and northwest, Austria to the south and Slovakia to the east. The Czech RepublicWaxes are used to make wax paper The practice of oiling parchment or paper in order to make it semi-translucent or moisture-proof goes back at least to medieval times. The invention of wax paper is credited to Thomas Edison or Thomas Conners, one of his assistants.[citation needed] Wax paper is commonly used in cooking, for its non-stick properties, and wrapping food for storage,, impregnating and coating paper Coated paper is paper which has been coated by a compound to impart certain qualities to the paper, including weight and surface gloss, smoothness or ink absorbency. Kaolinite and calcium carbonate are most often used for coating papers used in commercial printing. Other process can be poly olefin extrusion coating or silicone coating to make and card to waterproof it or make it resistant to staining, or to modify its surface properties. Waxes are also used in shoe polishes Shoe polish , usually a waxy paste or a cream, is a consumer product used to polish, shine, waterproof, and restore the appearance of leather shoes or boots, thereby extending the footwear's life. In some regions—including New Zealand—"Nugget" is used as a common term for solid waxy shoe polish, as opposed to liquid shoe polishes, wood polishes Wood finishing refers to the process of embellishing and/or protecting the surface of a wooden material. The process starts with surface preparation, either by sanding by hand , scraping, or planing. Imperfections or nail holes on the surface may be filled using wood putty or pores may be filled using wood filler. Often, the wood's colour is, and automotive polishes, as mold release agents in mold making, as a coating for many cheeses, and to waterproof leather and fabric. Wax has been used since antiquity as a temporary, removable model in lost-wax casting of gold, silver and other materials.
Wax with colorful pigments added has been used as a medium in encaustic painting, and is used today in the manufacture of crayons and colored pencils. Carbon paper, used for making duplicate typewritten documents was coated with carbon black suspended in wax, typically montan wax, but has largely been superseded by photocopiers and computer printers. In another context, lipstick and mascara are blends of various fats and waxes colored with pigments, and both beeswax and lanolin are used in other cosmetics. Also, the sports of surfing, skiing, snowboarding and skateboarding often use wax to enhance the performance. Beeswax or coloured synthetic wax is used to decorate Easter eggs in Ukraine and the Czech Republic. Paraffin wax is used in making chocolate covered bon-bons. Wax is also used in wax bullets, which are used as simulation aids.
Wax types
Animal waxes
- Beeswax - produced by honey bees
- Chinese wax - produced by the scale insect Ceroplastes ceriferus
- Earwax - found in the human ear.
- Lanolin (wool wax) - from the sebaceous glands of sheep
- Shellac wax - from the lac insect Kerria lacca
- Spermaceti - from the head cavities and blubber of the sperm whale
Vegetable waxes
- Bayberry wax - from the surface wax of the fruits of the bayberry shrub, Myrica faya
- Candelilla wax - from the Mexican shrubs Euphorbia cerifera and Euphorbia antisyphilitica
- Carnauba wax - from the leaves of the Carnauba palm, Copernica cerifera
- Castor wax - catalytically hydrogenated castor oil
- Esparto wax - a byproduct of making paper from esparto grass, (Macrochloa tenacissima)
- Japan wax - a vegetable triglyceride (not a true wax), from the berries of Rhus and Toxicodendron species
- Jojoba oil - a replacement for spermaceti, jojoba is pressed from the seeds of the jojoba bush, Simmondsia chinensis
- Ouricury wax - from the Brazilian feather palm, Syagrus coronata.
- Rice bran wax - obtained from rice bran (Oryza sativa)
- Soy wax - from soybean oil
Mineral waxes
- Ceresin waxes
- Montan wax - extracted from lignite and brown coal
- Ozocerite - found in lignite beds
- Peat waxes
Petroleum waxes
- Paraffin wax - made of long-chain alkane hydrocarbons
- Microcrystalline wax - with very fine crystalline structure
- Petroleum jelly
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